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Jennifer Aniston and Brad Pitt

Nominated for her role in Friends, Aniston brings then-husband Pitt to the ceremony. (Photo: Kevin Mazur/WireImage)

Red Carpet Flashback! Brad and Jen and Angelina and Billy Bob at the 2002 Golden Globes

Fifteen years ago at the Golden Globes, A Beautiful Mind and Moulin Rouge! scored the top movie prizes, and the A-list couples in attendance included Brad Pitt and then-wife Jennifer Aniston and Angelina Jolie and then-husband Billy Bob Thornton. In advance of Sunday night's ceremony (airing at 8 p.m. on NBC), let’s take a look at back at the stars who hit the red carpet for the 59th Golden Globes ceremony on Jan. 20, 2002.